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Question

The enthalpy of vapourisation of \(CCl_4~ 30.5~kJ~mol^{-1}\) is Calculate the heat required for the vapourisation of \(284~g\) of \(CCl_4\) at constant pressure. (Molar mass of \(CCl_4 = 154~g~mol^{-1}\))

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Solution

The enthalpy of vapourisation \((\Delta H)\) of \(CCl_4 = 30.5~kJ~mol^{-1}\)

\(q_p = \Delta H = 30.5~kJ~mol^{-1}\)

No.of moles of \(CCl_4 = \dfrac{given~mass(g)}{molar~mass~(g~mol^{-1})}\)

\(=\left ( \dfrac{284~g}{154~g~mol^{-1}} \right )\)

\(= 1.844~mol\)

Hence, the heat required for the vapourisation of \(1.844~mol\) of \(CCl_4\) at constant pressure

\(= 1.844~mol \times 30.5~kJ~mol^{-1}\)

Heat required \(= 56.24~kJ\)

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