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Question

The enthalpy of vapourisation of water from the following equations is:
H2(g)+12O2(g)H2O(l),H=286 kJ
H2(g)+12O2(g),H2O(g),H=245.5 kJ

A
6.02 kJ
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B
40.5 kJ
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C
62.3 kJ
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D
1.25 kJ
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Solution

The correct option is B 40.5 kJ
H2(g)+12O2(g)H2O(l),H=286 kJ...(i)
H2(g)+12O2(g),H2O(g),H=245.5 kJ...(ii)

The desired equation is H2O(l)H2O(g),H= ?

On subtracting equation (i) from (ii),
H2O(l)H2O(g)
(Equation (ii) - Equation (i))
H=245.5 kJ(286 kJ)=40.5 kJ

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