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Question

The equation of state of a gas is given by (P+av3)(V−b2)=cT, where P, V, T are pressure, volume and temperature respectively, and a, b, c are constants. The dimensions of a and b are respectively

A
ML8T2 and L3/2
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B
ML5T2 and L3
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C
ML5T2 and L
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D
ML6T2 and L3/2
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Solution

The correct option is A ML8T2 and L3/2
The dimensions of av3 must be that of pressure.
Dimension of pressure are [ML1T2]
Hence dimension of a is [ML1+33T2]=[ML8T2]
The dimension of b2 must be that of volume.
Hence [b2]=[L3]
[b]=[L3/2]

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