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Byju's Answer
Standard XII
Chemistry
Effective Equilibrium Constant
The equilibri...
Question
The equilibrium constant for the following reaction :
H
g
2
+
+
H
g
→
H
g
2
+
2
E
⊖
(
H
g
|
H
g
2
+
)
=
−
0.788
V
;
E
⊖
(
H
g
2
+
2
|
2
H
g
2
+
)
=
−
0.92
V
is
K
e
q
=
2.98
×
10
x
The value of
x
is ______.
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Solution
Anode :
H
g
→
H
g
2
+
+
2
e
−
E
⊖
r
e
d
=
0.788
V
Cathode :
2
H
g
⊕
+
2
e
−
→
H
g
2
+
2
E
⊖
(
r
e
d
)
=
0.92
V
At equilibrium,
E
⊖
c
e
l
l
=
0.059
2
l
o
g
K
e
q
⇒
0.92
−
0.788
=
0.059
2
l
o
g
K
e
q
⇒
0.132
×
2
0.059
=
l
o
g
K
e
q
⇒
K
e
q
=
2.98
×
10
4
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Similar questions
Q.
Calculate
K
c
for
H
g
2
+
+
H
g
⇌
H
g
2
+
2
.
Give that
E
o
2
H
g
/
H
g
2
+
=
−
0.788
V
and
E
o
H
g
2
+
2
/
2
H
g
2
+
=
−
0.920
V
.
Write answer as nearest integer after dividing by 100.
Q.
H
g
2
+
2
+
2
e
−
→
2
H
g
⟹
E
0
=
0.789
V
H
g
2
+
+
2
e
−
→
H
g
⟹
E
0
=
0.854
V
Calculate the equilibrium constant for
H
g
2
+
2
→
H
g
+
H
g
2
+
.
Q.
Element
H
g
has two oxidation states
H
g
1
+
&
H
g
2
+
, the correct order of radii of these ions?
Q.
For the equilibrium,
H
g
2
+
2
(
a
q
)
⇌
H
g
(
l
)
+
H
g
2
+
(
a
q
)
the equilibrium constant is approximately equal to
10
3
. Therefore,
Q.
Which statement(s) is/are correct ?
i. In oxymercuration and demercuration reaction, the electrophile is
A
c
O
H
⊕
.
ii. In this reaction,
H
g
+
is reduced to
H
g
∘
.
iii. In this reaction,
H
g
2
+
is reduced to
H
g
+
.
iv. In this reaction,
H
g
2
+
is reduced to
H
g
∘
.
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