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Byju's Answer
Standard XII
Chemistry
Equilibrium Constant from Nernst Equation
The equilibri...
Question
The equilibrium constant for the reaction,
S
n
(
s
)
+
2
H
+
→
S
n
2
+
+
H
2
(
g
)
a
t
25
∘
C
is:
E
∘
(
S
n
2
+
|
S
n
)
=
0.14
A
5.5
×
10
4
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B
2.3
×
10
2
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C
1.1
×
10
2
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D
1.009
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Solution
The correct option is
B
1.009
S
n
+
2
H
+
⟶
S
n
2
+
+
H
2
E
c
e
l
l
=
E
H
+
/
H
2
−
E
S
n
2
+
/
S
n
=
0
−
0.14
=
−
0.14
V
log
K
e
q
=
0.059
2
(
+
0.14
)
log
K
e
q
=
4.13
×
10
−
3
K
e
q
=
1.009
Suggest Corrections
0
Similar questions
Q.
Calculate the equilibrium constant for the reaction:
3
S
n
(
s
)
+
2
C
r
2
O
2
−
7
+
28
H
+
→
3
S
n
+
4
+
4
C
r
3
+
+
14
H
2
O
E
∘
for
S
n
/
S
n
2
+
=
0.136
V
E
∘
for
S
n
2
+
/
S
n
4
=
−
0.154
V
E
∘
for
C
r
2
O
2
−
7
/
C
r
3
+
=
1.33
V
, if the ans is
K
=
10
c
, what is c?
Q.
Using Nernst equation for the cell reaction,
P
b
+
S
n
2
+
→
P
b
2
+
+
S
n
Calculate the ratio
[
P
b
2
+
]
[
S
n
2
+
]
for which
E
c
e
l
l
=
0
.
(Given:
E
∘
P
b
/
P
b
2
+
=
0.13
v
o
l
t
and
E
∘
S
n
2
+
/
S
n
=
−
0.14
v
o
l
t
).
Q.
For an electrochemical cell
S
n
(
s
)
|
S
n
2
+
(
a
q
.
,
1
M
)
|
|
P
b
2
+
(
a
q
.
,
1
M
)
|
P
b
(
s
)
the ratio
[
S
n
2
+
]
[
P
b
2
+
]
when this cell attains equilibrium is
. (Given:
E
∘
S
n
2
+
S
n
=
−
0.14
V
;
E
∘
P
b
2
+
P
b
=
−
0.13
V
,
2.303
R
T
F
=
0.06
V
)
.
Q.
The standard emf of the following electrodes are;
E
∘
F
e
3
+
/
F
e
2
+
=
+
0.77
V
;
E
∘
S
n
2
+
/
S
n
=
−
0.14
V
under standard conditions, the potential for the reaction,
S
n
(
s
)
+
2
F
e
3
+
(
a
q
)
→
2
F
e
2
+
(
a
q
)
+
S
n
2
+
(
a
q
)
is:
Q.
The reaction,
2
B
r
−
(
a
q
)
+
S
n
2
+
(
a
q
)
→
B
r
2
(
1
)
+
S
n
(
s
)
with the standard potentials,
E
∘
S
n
=
−
0.114
V
,
E
∘
B
r
2
=
+
1.09
V
, is:
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