The equilibrium constant of a 2 electron redox reaction at 298 K is 3.8×10–3. The cell potential Eo (in V) and the free energy change △Go (in kJmol–1) for this equilibrium respectively, are:
A
-0.071, -13.8
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B
-0.071, 13.8
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C
0.71, -13.8
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D
0.071, -13.8
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Solution
The correct option is B -0.071, 13.8 ΔGo=−RTlnK=−8.314Jmol−1K−1×298K×2.303log(3.8×10−3)=13.809kJmol−1ΔGo=−nFEo13809=−2×96500EoEo=−0.071V