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Question

The equilibrium constant of the reaction A2(g)+B2(g)2AB(g) at 373 K is 50. If 1L of flask containing 1 mole of A2 (g) is connected to 2L flask containing 2 moles
B2(g) at 100oC, the amount of AB produced at equilibrium at 100oC would be

A
0.93 mol
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B
1.87 mol
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C
2.80 mol
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D
3.74 mol
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Solution

The correct option is B 1.87 mol
A2(g)+B2(g)2AB(g)Initially:13(M) 23(M)At equilibrium:(13x)M (23x)(M) 2x(M)Keq=50=4x2(13x)(23x)or 50=36x2(13x)(23x)or 50(9x29x+2)=36x2or 450x2450x+100=36x2or 414x2450x+100=0or x=+450(450)24×414×1002×414or x=+450(2025001656002×414or x=450369002×414=450192.12×414=0.31(M)moles of AB produced=2×0.31×3=1.86

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