The equilibrium constant of the reaction A2(g)+B2(g)⇌2AB(g) at 373 K is 50. If 1L of flask containing 1 mole of A2 (g) is connected to 2L flask containing 2 moles B2(g)at100o−C, the amount of AB produced at equilibrium at 100o−C would be
A
0.93 mol
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B
1.87 mol
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C
2.80 mol
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D
3.74 mol
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Solution
The correct option is B 1.87 mol A2(g)+B2(g)⇌2AB(g)Initially:13(M)23(M)Atequilibrium:(13−x)M(23−x)(M)2x(M)Keq=50=4x2(13−x)(23−x)or50=36x2(1−3x)(2−3x)or50(9x2−9x+2)=36x2or450x2−450x+100=36x2or414x2−450x+100=0orx=+450−√(450)2−4×414×1002×414orx=+450−√(202500−1656002×414orx=450−√369002×414=450−192.12×414=0.31(M)∴molesofABproduced=2×0.31×3=1.86