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Question

The equilibrium established in a reaction vessel of 2.5L capacity. The amounts of N2 and O2 taken at the start were respectively 2 moles and 4 moles. Half a mole of nitrogen has been used up at equilibrium. The molar concentration of nitric oxide is:


N2+O22NO

A
0.2
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B
0.4
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C
0.6
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D
0.1
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Solution

The correct option is A 0.4
N2+O22NO

Time=0 2 mol 4 mol

Time= eq2α4α2α
α=0.5mole

20.540.52(0.5)

Molarity=No. of molesVolume of solution(L)

Moles of NO=2×0.5
=1

Volume given = 2.5 L

Molar concentration of nitric Oxide is 12.5=0.4 M

Hence, option B is correct.

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