The equilibrium established when HgCl2 is shaken with an excess of Hg is:
A
Hg2++Hg⇌2Hg+
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B
Hg2++Hg(l)⇌Hg2+2
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C
Hg+2Hg2+⇌Hg2++2Hg+
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D
no equilibrium is established
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Solution
The correct option is BHg2++Hg(l)⇌Hg2+2 As we have given thatHg+22 disproportionates and forms Hg(l)andHg+2 at equilibrium , so If we take HgCl2 and Hg it will comproportionate and Hg+22 will form at equilibrium.