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Question

The equilibrium mixture for 2SO2(g)+O2(g)2SO3(g) present in 1L vessel at 600pC contains 0.50, 0.12, and 5.0 mole of SO2,O2 and SO3 respectively.
Also calculate Kp

A
11.62 atm1
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B
21.62 atm1
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C
31.62 atm1
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D
18.62 atm1
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Solution

The correct option is A 11.62 atm1
​The equilibrium reaction is 2SO2(g)+O2(g)2SO3(g).
The expression for th eequilibrium constant is Kc=[SO3]2[SO2]2[O2]
Substitute values in the above expression.
Kc=(5)2(0.5)2×0.12=833.33 mol1L
Kp=Kc(RT) ng
where ng = (total gas molecules in product) - (total gas molecule in the reactant)
In this case ng = 2-3 = -1
Kp=Kc(RT)1=833.330.0821×873=11.62 atm1

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