The equilibrium mixture for 2SO2(g)+O2(g)⇌2SO3(g) present in 1L vessel at 600pC contains 0.50, 0.12, and 5.0 mole of SO2,O2andSO3 respectively.
Also calculate Kp
A
11.62atm−1
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B
21.62atm−1
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C
31.62atm−1
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D
18.62atm−1
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Solution
The correct option is A11.62atm−1 The equilibrium reaction is 2SO2(g)+O2(g)⇌2SO3(g).
The expression for th eequilibrium constant is Kc=[SO3]2[SO2]2[O2]
Substitute values in the above expression. Kc=(5)2(0.5)2×0.12=833.33mol−1L Kp=Kc(RT)△ng
where △ng = (total gas molecules in product) - (total gas molecule in the reactant)
In this case △ng = 2-3 = -1 Kp=Kc(RT)−1=833.330.0821×873=11.62atm−1