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Question

The equilibrium SO2Cl2(g)SO2(g)+Cl2(g) is attained at 25oC in a closed container and an inert gas, helium, is introduced. Which of the following statements is/are correct?

A
The concentrations of SO2,Cl2,and SO2Cl2 change.
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B
More chlorine is formed
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C
The concentration of SO2 is reduced
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D
All are incorrect
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Solution

The correct option is D All are incorrect
At constant volume, there is no effect of addition of inert gas to a reaction in equilibrium. At constant pressure, for the reactions for which Δn=0. there is no effect of addition of inert gas to a reaction in equilibrium. At constant pressure, for the reactions for which Δn0, the equilibrium shifts in the direction of more number of moles.

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