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Question

The equivalent conductance of C6H5COONa, HCl and NaCl at infinite dilution are 82.4, 426.2 and 126.5 Ω1cm2. Calculate the equivalent conductance (Ω1cm2) of benzoic acid at infinite dilution.

A
217.3 Ω1cm2
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B
272.1 Ω1cm2
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C
191.05 Ω1cm2
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D
382.1 Ω1cm2
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Solution

The correct option is D 382.1 Ω1cm2
From Kohlrauch's law, we get
λC6H5COOH=λC6H5COONa+λHClλNaCl=82.4+426.2126.5=382.1 Ω1cm2

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