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Question

The equivalent point in a titration of 40.0 mL of a solution of a weak monoprotic acid occurs when 35.0 mL of a 0.10 M NaOH solution has been added. The pH of the solution is 5.75 after the addition of 20.0 mL of NaOH solution. What is the dissociation constant of the acid?

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Solution

Va=40ml, Vb=35ml, NaOH molarity=0.1M pH=5.5
H1V1=M2V2
M1=0.1×3540=0.0875M
pH=log[H+]
[H+]=1045
[H+]=3.16×106
HAH++A
Ka=[H+][A][HA]
[H+]=[A]
Ka=(3.16×106)20.0875
Ka=1.1×1010
Dissociation Constant of acid=1.1×1010

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