The correct option is B Hund's rule
The explanation for the presence of three unpaired electrons in the nitrogen atom can be given by Hund's rule. According to this rule, electron pairing in any orbital (s, p, d or f) cannot take place until each orbital of the same sublevel contains 1 electron. The electronic configuration of N is 1s22s22p3.
2p orbital has 3 sub-levels each of which will contain one electron. Pairing will occur only if the fourth electron is added.