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Question

The filtrate of group II has been given to you for analysis of group III ( which may contain Fe2+,Cr3+ and Al3+). mention systematic steps you would follow


Step I : Boil off H2S
Step II : Add a drop of HNO3 (to oxide Fe2+ to Fe3+)
Step III:Add NH4Cl boil, cool and add NH4OH

Which of following is correct option?

A
Step I and Step II are wrong
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B
Only Step II is wrong
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C
Step I and Step III are wrong
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D
All steps are correct
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Solution

The correct option is D All steps are correct
Step I: The filtrate of group II is boiled to remove hydrogen sulphide.
Step II: A drop of nitric acid is added which oxidizes ferrous ions (if present) to ferric ions.
Step III: Ammonium chloride is added and the solution is boiled, cooled and ammonium hydroxide is added.

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