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Question

The final products formed when acetylene reacts with HCN & CH3COOH separately,respectively are :

A
CH3CH(CN)2 & CH3CH(OCOCH3)2
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B
CH3CH(CN)2 & CH2=CH(OCOCH3)
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C
CH2=CHCN & CH3CH(OCOCH3)2
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D
CH2=CHCN & CH2=CH(OCOCH3)
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Solution

The correct option is A CH3CH(CN)2 & CH3CH(OCOCH3)2
HCCAcetyleneHHCN−−−−−Cu2(CN)2CH2=CHCN(Vinyl Cyanide) −−HCNCH3CH(CN)2

HCCAcetyleneHCH3COOH−−−−−−Hg2+H2C=CH(OCOCH3)
CH3COOH−−−−−−HG2+CH3CH(OCOCH3)2
Ethylidine acetate

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