The first ionisation energy of Be is smaller than that of B while the second ionisation energy of Be is higher than that of B. Answer whether the above statement is true or false. If true enter 1, else enter 0.
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Solution
The first ionisation energy of Be is higher than that of B while the second ionisation energy of Be is smaller than that of B.
The ionization of Be requires removal of an electron from the 2s subshell. Ionization of B, however, requires removal of an electron from a 2p subshell. The 2p subshell is higher in energy than the 2s subshell (this why we fill the 2s subshell first when constructing an electron configuration) resulting in a lower than expected first ionization energy for boron.
While the removal of second electron from B is difficult as it is to be removed from a completely filled 2s orbital while the removal of second electron from Be is comparatively easier as it is to be removed from a half filled 1s orbital.