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Question

The first ionisation energy of Na,Mg,Al and Si are in the order of:

A
Na<Mg>Al<Si
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B
Na>Mg>Al>Si
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C
Na<Mg<Al>Si
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D
Na>Mg>Al<Si
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Solution

The correct option is A Na<Mg>Al<Si
Mg requires greater ionization energy than Al due to its configuration. It is more difficult to remove an electron from 3s orbital than from 3p orbital since s-orbitals have greater penetration power. Moreover, Mg has a stable electronic configuration with full-filled 3s orbital.
Among Na and Mg, Mg has completely filles sorbital, hence, ionization energy of Mg is greater than Na.

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