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Question

The first ionization potentials (eV) of Be and B respectively are

A
8.29eV,8.29eV
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B
9.32eV,9.32eV
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C
8.29eV,9.32eV
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D
9.32eV,8.29eV
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Solution

The correct option is C 9.32eV,8.29eV
First ionisation potential of Be is greater than boron due to stable cofiguration.
4Be=1s2,2s2
5B=1s2,2s22p1
Order of attraction of electrons towards nucleus is 2s>2p, Therefore more amount of energy is required to remove the electron from 2s orbital in comparission to 2p orbital.Therefore ionisation potential of Be is 9.32eV and B is 8.29eV.

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