The first order reflection of a beam of X-rays of wavelength 1.54∘A from the (100) face of a crystal of the simple cubic type occurs at an angle of 11.29∘. Calculate the length of the unit cell.
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Solution
Applying Bragg's equation, 2dsinθ=nλ Given, θ=11.29∘,n=1,λ=1.54∘A=1.54×10−8cm d=1.54×10−82×sin11.29∘=1.54×10−82×0.1957=3.93×10−8cm dhkl=a√h2+k2+l2=a a=3.93×10−8cm= length of the unit cell.