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Question

The first order reflections of a beam of X – rays of wavelength of 1.54˙A from the (100) face of a crystal of the simple cubic type occurs at an angle 11.29. Calculate the length of the unit cell.

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Solution

Applying Bragg’s equation
2dSinθ=nλ
Given θ=11.29,λ=1.54˙A=1.54×108cm
n=1
d=1.54×1082×Sin11.29=1.54×1082×0.1957=3.93×108cm
dhkl=ah2+k2+l2=a
a=3.93×108cm (length of the unit cell)

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