The first order reflections of a beam of X – rays of wavelength of 1.54˙A from the (100) face of a crystal of the simple cubic type occurs at an angle 11.29∘. Calculate the length of the unit cell.
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Solution
Applying Bragg’s equation 2dSinθ=nλ Given θ=11.29∘,λ=1.54˙A=1.54×10−8cm n=1 d=1.54×10−82×Sin11.29∘=1.54×10−82×0.1957=3.93×10−8cm dhkl=a√h2+k2+l2=a a=3.93×10−8cm (length of the unit cell)