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Question

The following reaction was carried out in water, Cl2+2II2+2Cl.
The initial concentration of I was 0.25 mol L1 and the concentration after 10 minutes was 0.23 mol L1. Calculate the rate of disappearance of I and appearance of I2.

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Solution

Δ[I]=[I]final[I]initial
=0.230.25=0.02 mol L1
Δt=100=10 min
Δ[I]Δt=(0.02)10=0.002 mol L1 min1
Rate of appearance of I2=12Δ[I]Δt=0.0022
=0.001 mol L1 min1
=1×103 mol L1 min1

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