The following rearrangements involve the formation of isocyanate intermediate
A
Hoffmann rearrangement
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B
Curtius rearrangement
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C
Wolff rearrangement
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D
Lossen rearrangement
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Solution
The correct options are A Hoffmann rearrangement B Curtius rearrangement D Lossen rearrangement R – N = C = 0 is involved in A, B, D only. ‘C’ involves ketene intermediate.