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Question

The following statements relate to the adsorption of gases on a solid surface.


Identify the incorrect statement among them :

A
Enthalpy of adsorption is negative.
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B
On adsorption, the residual forces on the surface are increased.
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C
On adsorption, decrease in surface energy appears as heat.
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D
Entropy of adsorption is negative.
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Solution

The correct option is B On adsorption, the residual forces on the surface are increased.
(A) Enthalpy of adsorption is negative as heat is liberated during adsorption. The process is exothermic.

Hence, statement A is correct.

(B) On adsorption, the residual forces on the surface are decreased as the surface is covered with the substance being adsorbed which develops forces between absorbate and adsorbent.

Hence, statement B is incorrect.

(C) On adsorption decreases in surface energy appears as heat.
This makes the process exothermic.

Thus, statement C is correct.

(D) Entropy of adsorption is negative as there is a decrease in the disorder.

Hence, the statement D is correct.

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