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Question

The following two reactions are known
Fe2O3(s)+3CO(g)2Fe(s)+3CO2(g);ΔH=26.8 kJ

FeO(s)+CO(g)Fe(s)+CO2(g);ΔH=16.5 kJ

The value of ΔH for the following reaction

Fe2O3(s)+CO(g)2FeO(s)+CO2(g) is

A
+10.3 kJ
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B
-43.3 kJ
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C
-10.3 kJ
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D
+6.2 kJ
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Solution

The correct option is D +6.2 kJ
As Given in above,Fe2O3(s)+3CO(g)2Fe(s)+3CO2(g); ΔH=26.8 kJ ...(i)

FeO(s)+CO(g)Fe(s)+CO2(s);ΔH=16.5 kJ ...(ii)

Fe2O3(s)+CO(g)2FeO(s)+CO2(g); ΔH=? ...(iii)

Eq. (iii) can be obtained as:

(i) -(ii) = -26.8 - 2(-16.5) = -26.8 + 33.0 = +6.2 kJ
the correct option is (d).

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