The following water gas shift reaction is an i portant industrial process for the prodicution of hydrogen gas. CO(g)+H2O(g)⇌CO2(g)+H2(g) At a given temperature Kp=2.7. If 0.13mol of CO,0.56mol of water, 0.78mol of CO2 and 0.28mol of H2 are introduced into a 2L flask, and find out in which direction must the reaction proceed to reach equilibrium:
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Solution
At a given temp
Keq=2.7
At given time, Q=[CO2][H2][CO][H2O]=0.78×0.280.13×0.56
Q=3
Since Q>Keq
(as 3>2.7)
The concentration of
products is more so reaction occurs in backward direction