The force of attraction between the positively charged nucleus and the electron in a hydrogen atom is given by f=ke2r2. Assume that the nucleus is fixed. The electron, initially moving in an orbit of radius R1 jumps into an orbit of smaller radius R2 . the decreases in the total energy of the atom is.
It is given that,
f=ke2r2
This force is balanced by the centripetal force.
fc=ke2r2
mv2r=ke2r2
mv2=ke2r
Kinetic energy of electron is =12mv2=12ke2R
The electron is moving in a circle of radius R1 and jumps into the circle of radius R2.
So,
ΔK=12ke2[1R2−1R1]............(1)
Potential energy is
ΔU=−R2∫R1f.dr
=−R2∫R1ke2r2dr
=−ke2(1R2−1R1)
So, change in total energy is
ΔE=ΔK+ΔU
=12ke2[1R2−1R1]+−ke2(1R2−1R1)
=−12ke2(1R2−1R1)
or
ΔE=12ke2(1R1−1R2)