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Electrolysis and Electrolytes

The formal po...

Question

The formal positive charge on nitrogen of nitro group makes it a strong :

A

Electron withdrawing group

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B

Acid

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C

Both a and b

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D

None of above

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Solution

The correct option is A Electron withdrawing group
The formal positive charge on nitrogen of nitro group makes it a strong electron withdrawing group and exerts a strong pull on neighboring electrons.

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Similar questions

Q. Assertion :Gabriel phthalimide reaction is used for the preparation of

C_{2} H_{5} {N H}_{2}

and p-nitro aniline Reason:

S_{N} 2

reaction takes place with

1^{o} R X

1^{o} A r X

containing electron withdrawing group at

o -

p -

Statement 1: The Friedel-Craft alkylation of nitro-benzene gives metals alkylated nitro benzene.

Statement 2: Nitro group is metal directing aromatic electrophilic substitution as it decreases electron density at o & p position.

Comment on the above statement.

Q. Why can't Lialh4 be used to reduce nitro benzene to aniline. It is a strong so shouldn't it reduce the nitro group

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- {N O}_{2}

- {N H}_{2}

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