The formation of polyethylene from calcium carbide takes places as follows : CaC2+2H2O→Ca(OH)2+C2H2 C2H2+H2→C2H4 nC2H4→(CH2−CH2)n The amount of polyethylene obtained from 64 kg of CaC2 is :
A
14 kg
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B
7 kg
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C
21 kg
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D
28 kg
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Solution
The correct option is B28 kg
Mass of CaC2 = 64 Kg
Moles of CaC2 = 64/64 = 1000 mol
CaC2+2H2O→Ca(OH)2+C2H2
For 1000 mole of CaC2 , We get 1000 mole of C2H2
C2H2+H2→C2H4
For 100 mole of C2H2 , we get 1000 mole of C2H4
nC2H4→(CH2−CH2)n
For n mole C2H2 , we get 1 mole of polyethylene.
For 1000 mole of C2H2 , we get (1000n)×1
Number of moles of polyethylene formed are 1000/n.
Molecular weight of polyethylene is n×[(2×12)+(2×4)]=28n
Mass of polyethylene produced = Number of moles × Molecular weight