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Question

The formation of the oxide ion (O2(g)) required first an exothermic and then an endothermic step as shown below.
O+eO (g)+142 kJ mol1

O+eO2 (g)844 kJ mol1

This is because:

A
oxygen is more electronegative
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B
oxygen has high electron affinity
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C
O ion lends to resist the addition of another electron
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D
O ion has comparatively larger size than oxygen atom.
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Solution

The correct options are
B oxygen has high electron affinity
C O ion lends to resist the addition of another electron
An oxygen atom has a high affinity towards electron hence the energy is released while one electron is added to it. However, the O ion repels the incoming electron and hence the second step is endothermic.

Hence answer for the given question is options B & C.

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