The formation of the oxide ion (O2−(g)) required first an exothermic and then an endothermic step as shown below. O+e−→O−(g)+142kJmol−1
O−+e−→O−2(g)−844kJmol−1
This is because:
A
oxygen is more electronegative
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B
oxygen has high electron affinity
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C
O− ion lends to resist the addition of another electron
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D
O− ion has comparatively larger size than oxygen atom.
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Solution
The correct options are B oxygen has high electron affinity CO− ion lends to resist the addition of another electron An oxygen atom has a high affinity towards electron hence the energy is released while one electron is added to it. However, the O− ion repels the incoming electron and hence the second step is endothermic.
Hence answer for the given question is options B & C.