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Question

The formula of dichlorobis(urea)copper(II) is:

A
[Cu(O=C(NH2)2)2]Cl2
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B
[CuCl2(O=C(NH2)2)2]
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C
[Cu(O=C(NH2)2)]Cl
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D
[CuCl2(O=C(NH2)2)H2]
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Solution

The correct option is B [CuCl2(O=C(NH2)2)2]
In this complex, 2 'chloro' ligands and 2 'urea' ligands are present. By following alphabetical order, chloro comes first with its number (i.e., dichloro) followed by the second ligand (O=C(NH2)2)2. Since, it is a bidentate ligand (i.e., can attach at more than one binding sites), the prefix 'bis' is used followed by the name of ligand urea. Cu oxidation state will be +2 (x2=0). So, the correct answer is [CuCl2(O=C(NH2)2)2].

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