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Byju's Answer
Standard XII
Chemistry
Chlorides of Phosphorus
The four sets...
Question
The four sets of shape and hybridization of xenon oxyfluorides are given. Choose the wrong set.
A
X
e
O
F
2
- T-Shape -
s
p
3
d
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B
X
e
O
F
4
-Square pyramidal -
s
p
3
d
2
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C
X
e
O
2
F
2
- Distorted trigonal bipyramidal -
s
p
3
d
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D
X
e
O
3
F
2
- Octahedral -
s
p
3
d
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Solution
The correct option is
A
X
e
O
3
F
2
- Octahedral -
s
p
3
d
The structure
X
e
O
3
F
2
is given.
No. of lone pair of
X
e
=
0
and no. of bond pair
=
5
Hybridisation of
X
e
=
s
p
3
d
Hence, the shape of
X
e
O
3
F
2
should be trigonal bipyramidal and not octahedral.
Therefore, option
D
is correct.
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Similar questions
Q.
Which of following is correct set ?
Species
Hybridisation
shape
X
e
F
2
sp
Linear
X
e
O
2
F
2
s
p
3
Tetrahedral
X
e
O
F
4
s
p
3
d
2
Square pyramidal
X
e
O
3
s
p
3
d
Trigonal pyramidal
Q.
The structure and hybridization of
B
r
F
5
are
Q.
Structure and hybridisation of
I
F
7
Q.
Assertion :
P
F
5
and
B
r
F
5
appear to have similar formulae, but structures are different. Reason:
P
F
5
:
s
p
3
d
trigonal bipyramidal,
B
r
F
5
s
p
3
d
2
square based pyramid.
Q.
The shape of
X
e
O
F
4
is
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