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Question

The four sets of shape and hybridization of xenon oxyfluorides are given. Choose the wrong set.

A
XeOF2 - T-Shape - sp3d
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B
XeOF4 -Square pyramidal - sp3d2
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C
XeO2F2 - Distorted trigonal bipyramidal - sp3d
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D
XeO3F2 - Octahedral - sp3d
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Solution

The correct option is A XeO3F2 - Octahedral - sp3d
The structure XeO3F2 is given.

No. of lone pair of Xe=0 and no. of bond pair=5

Hybridisation of Xe=sp3d

Hence, the shape of XeO3F2 should be trigonal bipyramidal and not octahedral.

Therefore, option D is correct.

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