The fraction of the total volume occupied by the atoms present in the simple cube is:
Let the edge length of the cube be a and radius of atom be r.
Now, in simple cube, number of atoms present =18×8=1
So, volume occupied =1×43πr3
Now, in simple cube atoms at corners will be touching each other.
⇒a=2r⇒r=a2
Volume of cube =a3
So, fraction of total volume occupied =43πr3a3
=43×π×(a2)3a3
=43×π×12
=π6