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Question

The freezing point of a diluted milk sample is found to be −0.2oC, while it should have been −0.5oC for pure milk. How much water has been added to pure milk. How much water has been added to pure milk to make the diluted sample?

A
2 cups of water to 3 cups of pure milk
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B
1 cup of water to 3 cups of pure milk
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C
3 cup of water to 2 cups of pure milk
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D
1 cup of water to 2 cups of pure milk
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Solution

The correct option is C 3 cup of water to 2 cups of pure milk
We have,
Tf=0.5oC (For milk) and Tf=0.2oC (For diluted solution)
ΔTf=0.5oC (For milk) and ΔTf=0.2oC (For diluted solution)
Now, we know,
ΔTf=Kf×m
where m=molality
We can have,
(ΔTf)1(ΔTf)2=Kf×x×1000w2w1×Kf×x×1000
\dfrac{0.5}{0.2}=\dfrac{w-2}{w-1}$
w2=52w1
Wwater=52w1w1=23w1
Thus, we required 3 cup of water and 2 cup of milk

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