The frequency of radiation emitted when the electron falls from n = 4 to n = 1 in a hydrogen atom will be (given ionization energy of H=2.18×10−18 atom−1 and h=6.606×10−34 j − s)
v=CRHZ2(1n21−1n22)
=3×108×1.1×107×12(112−142)
=3.3×1015(1516)
=3.3×1015×0.9375
=3.08×1015s−1