The frequency of revolution of an electron in nth orbit is fn. If the electron makes a transition from the nth orbit to (n−1)th orbit, then the relation between the frequency (v) of emitted photon and fn will be :
f= mZ2e4/4n3h3ϵ02
f(n-1)=fn.(n/n-1)^3
and
E=-mZ2e4/8ε02h2n2
so, E=-fhn/2
now for transition within n to (n-1)
hv=f(n).h.n/2-f(n-1).h.n/2
v=f(n)/2{[n^4-(n-1)^4]/n^3}
so v=Kf(n)
v proportional to f(n) but some of its multiple