The correct option is A methyl isocyanide
Ethane nitrile is CH3C≡N.
A) Ethyl carbylamine is C2H5−fN≡C
B) Methanenitrile is HCN
C) Methyl carbylamine is CH3−fN≡C
D) Propanenitrile is CH3 CH2 C≡N
Ethanenitrile (CH3CN) and methyl carbylamine (CH3NC) have same molecular formula but different functions groups so, they are functional isomer.