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Question

The fusion of chromite ore (FeCr2O4) with Na2CO3 in air gives a yellow solution upon addition of water. Subsequent treatment with H2SO4 produces an orange solution. The yellow and orange colours, respectively, are due to the formation of:

A
Na2CrO4 and Na2Cr2O7
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B
Cr(OH)3 and Na2Cr2O7
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C
Cr2(CO3)3 and Fe2(SO4)3
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D
Cr(OH)3 and Na2CrO4
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Solution

The correct option is A Na2CrO4 and Na2Cr2O7
4FeCr2O4+8Na2CO3+7O28Na2CrO4+2FeO3+8CO2

Na2CrO4+H2SO4Na2Cr2O7+Na2SO4+H2O

Yellow -----> Na2CrO4

Orange ----> Na2Cr2O7

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