The gas A2 in the left flask allowed to react with gas B2 present in right flask at A2(g)+B2(g)⇌2AB(g),KC=4 at 27∘C. What is the concentration of AB when equilibrium is established?
A
1.33M
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B
0.66M
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C
0.33M
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D
2.66M
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Solution
The correct option is B0.66M
A2+B2⇌2ABKC=4
A2+B2⇌2AB
t=0240
t=teq2−x4−x2x
Total volume =1+3=4 lit
[AB]=2x4=x/2
[B2]=4−x4
[A2]=2−x4
KC=(x/2)2(4−x4)(2−x4)⇒4x2(4−x)(2−x)=4
x2=(4−x)(2−x)
x2=x2−6x+8
6x=8
x=4/3
concentration of AB is x/2=2/3=0.66M Hence, the correct option is B.