The correct option is A He (molecular mass 4)
Average speed (vav) of gas molecules is inversely proportional to the square root of the absolute temperature (T) of the gas
vav=√8RTπM
where R is gas constant and M the molecular weight
Given v1=v, M1=64,v2=4v
∴ v1v2=√M2M1
v4v=√M264
⇒M2=6416=4
hence, the gas is helium (molecular mass 4)