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Question

The given compound (Benzophenone) can be obtained by Friedel Crafts reaction of benzene with which of the following compounds?

A
Benzyl chloride
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B
Chlorobenzene
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C
Benzoyl chloride
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D
None of these
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Solution

The correct option is C Benzoyl chloride
Friedel Crafts Acylation:
In this reaction, one H-atom of the ring get replace by Acyl (RCO) group. The attacking electrophile is an acylium ion (RCO+) made available by the reaction of acid halide and an anhydrous lewis acid.
Here, benzene reacts with C6H5COCl in the presence AlCl3 to give C6H5COC6H5 (Benzophenone).
This reaction occurs by
(i) Formation of ayclium ion

(ii) Formation of Wheland intermediate

(iii) Removal of proton from the intermediate.



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