The correct option is A -6.04
For hydrogen like species, energy of nth shell is given by
(E)nth=(EGND)HX Z2n2
where,
(E)nth is the energy of nth state of hydrogen like species
(EGND)H is the ground state energy of hydrogen atom
Z is the atomic number
Thus,
E3rd(He+)=(−13.6 eV)X2232=−6.04 eV
Hence, correct option is (a).