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Question

The ground state energy of hydrogen atom is -13.6 eV. The energy of second excited state of He+ ion in eV is

A
-6.04
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B
-27.2
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C
-54.4
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D
-3.4
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Solution

The correct option is A -6.04
For hydrogen like species, energy of nth shell is given by
(E)nth=(EGND)HX Z2n2
where,
(E)nth is the energy of nth state of hydrogen like species
(EGND)H is the ground state energy of hydrogen atom
Z is the atomic number
Thus,
E3rd(He+)=(13.6 eV)X2232=6.04 eV
Hence, correct option is (a).

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