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Byju's Answer
Standard XII
Chemistry
Effect on Kc
The half-life...
Question
The half-life period is independent of the initial concentration of reactant when the reaction is:
A
first order
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B
second order
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C
zero order
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D
pseudo first order
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Solution
The correct option is
D
first order
Half-life Method
Relation between half-life period of a reaction and intial concentration is as follows :
t
1
/
2
∝
1
a
n
−
1
For first order reaction (Half life
∝
a
0
)
For second order reaction (Half life
1
/
a
)
For third order reaction (Half life
∝
1
/
a
2
)
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Similar questions
Q.
(A) Half-life of a first order reaction is independent of the initial concentration of reactant.
(R)
t
1
/
2
(first order)
=
τ
/
1.44
where,
τ
=
average life.
Q.
Show that the half-life period of a first order reaction is independent of the initial concentration of the reactant.
Q.
What is the half-life period of reaction? Justify from the rate equation for first-order reactions that the half-life period for such reaction is independent of the initial concentrations of the reactants.
Q.
The half life of a first order reaction is
30
m
i
n
and the initial concentration of the reactant is
0.1
M
. If the initial concentration of reactant is doubled, then the half life of the reaction will be:
Q.
Statement - I : If in a zero order reaction, the concentration of the reactant is doubled, the half-life period is also doubled.
Statement - Il: For a zero order reaction, the rate of reaction is independent of initial concentration.
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