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Question

The halides of group IIIA elements behave as lewis acids. The acceptor ability is maximum for halides of :

A
Tl
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B
Ga
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C
Al
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D
B
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Solution

The correct option is D B
Option (D) is correct.
The acceptor ability is maximum for halides of boron due to the availability of 3 valence electrons (2s22p1) for covalent bond formation using four orbitals (2s,2px,2pyand 2pz) leads to electron deficiency in boron compounds. This deficiency makes them good electron acceptor and thus boron compounds behave as lewis acids.

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