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The Hall-Heroult process is used industrially to prepare aluminium by the electrolysis of cryolite (or Na3AlF6).
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Solution

The Hall-Heroult process is used industrially to prepare aluminium by the electrolysis of cryolite (or Na3AlF6).
4AlF3 (from cryolite) 4Al3++12F
4Al3++12e4Al (reduction at cathode)

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