The heat of formation of NO from its elements is +90kjmol−1. What is the approximate bond dissociation energy of the bond in NO? Bond Bond energy Bond Bond energy N=N 941kjmol−1 O=O 499kJmol−1
A
630 kJ.mol1
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B
720 k.J. mol1
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C
765 k.J.mol1
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D
810 k.J.mol1
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Solution
The correct option is A 630 kJ.mol1 12N2+12O2⟶NO Heat of formation = Bond dissociation energy of reactants-Bond dissociation energy of products 90=9412+4992−(NO) bond dissociation energy (NO) bond dissociation energy = 14002−90=720−90=630kJ