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Question

The hybridization of P in POCl3 and shape of POCl3 are, respectively:

A
sp3, tetrahedral
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B
sp3, pyramidal
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C
sp3, square planar
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D
sp3, distorted tetrahedral
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Solution

The correct option is D sp3, tetrahedral
In POCl3 structure, the no. of σ bonds are 4. Hence, the hybridization is sp3.
Shape of POCl3 is tetrahedral due to assymetric charge distribution around Phosphorous atom.
The correct option is (A).

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