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Question

The hydrated salt, Na2SO4.nH2O undergoes 56% loss in weight on heating and becomes anhydrous. The value of n (approx.) will be :

A
5
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B
3
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C
7
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D
10
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Solution

The correct option is C 10
100 g of Na2SO4.nH2O contians 56 g of water and 44 g of Na2SO4.

The molar mass of Na2SO4 is 23+23+32+4(16)=142g.

44 g of Na2SO4 corresponds to 56 g of water.

142 g of Na2SO4 will correspond to 142×5644=180 g of water.

This corresponds to 18018=10 moles.

Thus, the value of n is 10.

Hence, option D is correct.

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