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Byju's Answer
Standard XII
Chemistry
First Order Reaction
The hydrolysi...
Question
The hydrolysis of ethyl acetate is a reaction of:
C
H
3
C
O
O
C
2
H
5
+
H
2
O
H
+
−
−−−−−
→
C
H
3
C
O
O
H
+
C
2
H
5
O
H
A
zero order
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B
first order
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C
second order
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D
third order
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Solution
The correct option is
B
first order
H
+
C
H
3
C
O
O
C
2
H
5
+
H
2
O
⟶
C
H
3
C
O
O
H
+
C
2
H
5
O
H
In the above reaction medium of reaction is water which will be in excess, hence it can be avoided in rate expression, thus rate will be given as
R
a
t
e
=
K
[
C
H
3
C
O
O
C
2
H
5
]
Hence it is a
1
s
t
order reaction.
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Similar questions
Q.
The hydrolysis of ethyl acetate,
C
H
3
C
O
O
C
2
H
5
+
H
2
O
H
+
−
−
→
C
H
3
C
O
O
H
+
C
2
H
5
O
H
is a reaction of:
Q.
Assertion :The order of the reaction,
C
H
3
C
O
O
C
2
H
5
+
H
2
O
⇌
C
H
3
C
O
O
H
+
C
2
H
5
O
H
is
2
. Reason: The molecularity of this reaction is
2
.
Q.
The esterification of acetic anhydride by ethyl alcohol can be represented by the following balanced equation:
(
C
H
3
C
O
)
2
O
A
+
C
2
H
5
O
H
B
⟶
C
H
3
C
O
O
C
2
H
5
+
C
H
3
C
O
O
H
When the reaction is carried out in dilute hexane, rate is
k
[
A
]
[
B
]
. When ethyl alcohol is the solvent, rate is
k
[
A
]
.Explain the difference.
Q.
The rate of the reaction
C
H
3
C
O
O
C
2
H
5
+
N
a
O
H
→
C
H
3
C
O
O
N
a
+
C
2
H
5
O
H
is given as rate=
K
[
C
H
3
C
O
O
C
2
H
5
]
[
N
a
O
H
]
+
.If three times water is added to the reaction mixture,what will be the rate of the reaction compared to the original rate?
Q.
One mole of
C
H
3
C
O
O
H
and one mole of
C
2
H
5
O
H
reacts to produce
2
3
mol of
C
H
3
C
O
O
C
2
H
5
. The equilibrium constant is:
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